cp gnuplot gnuplot.bak
Rename it to gnuplot1:
mv gnuplot gnuplot1
Now create the script gnuplot by typing
emacs gnuplot
Create this script:
#!/bin/bash
/usr/bin/gnuplot1 -background white
Add execution permission through chmod +x gnuplot
It will make a standard call to gnuplot change to gnuplot -background white, which will change your plots background in octave.
If you have a better way to do this, please leave me a comment
Have fun :)